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Hard Water

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  •   Copper Ionization Iron In Water
    Hard Water

    I'm sure you've heard the terms 'hard water' and 'soft water', but do you know what they mean? Is one type of water somehow better than the other? What type of water do you have? Let's take a look at the definitions of these terms and how they relate to water in everyday life.

    What is Hard Water?
    Hard water is any water containing an appreciable quantity of dissolved minerals.

    What is Soft Water?
    Soft water is treated water in which the only cation (positively charged ion) is sodium.

    Chemical Free Pool

    The minerals in water give it a characteristic taste. Some natural mineral waters are highly sought for their flavor and the health benefits they may confer. Soft water, on the other hand, may taste salty and may not be suitable for drinking.

    If soft water tastes bad, then why might you use a water softener? The answer is that extremely hard water may shorten the life of plumbing and lessen the effectiveness of certain cleaning agents.

    When hard water is heated, the carbonates precipitate out of solution, forming scale in pipes and tea kettles. In addition to narrowing and potentially clogging the pipes, scale prevents efficient heat transfer, so a water heater with scale will have to use a lot of energy to give you hot water. Soap is less effective in hard water because its reacts to form the calcium or magnesium salt of the organic acid of the soap. These salts are insoluble and form grayish soap scum, but no cleansing lather. Detergents, on the other hand, lather in both hard and soft water. Calcium and magnesium salts of the detergent's organic acids form, but these salts are soluble in water.

    Hard water can be softened (have its minerals removed) by treating it with lime or by passing it over an ion exchange resin. The ion exchange resins are complex sodium salts. Water flows over the resin surface, dissolving the sodium. The calcium, magnesium, and other cations precipitate onto the resin surface. Sodium goes into the water, but the other cations stay with the resin. Very hard water will end up tasting saltier than water that had fewer dissolved minerals.

    Most of the ions have been removed in soft water, but sodium and various anions (negatively charged ions) still remain. Water can be de-ionized by using a resin that replaces cations with hydrogen and anions with hydroxide. With this type of resin, the cations stick to the resin and the hydrogen and hydroxide that are released combine to form pure water.

    Hard Water Problems

    Laundering in Hard Water
    Clothes washed in hard water often look dingy and feel harsh and scratchy. The hardness minerals combine with some soils to form insoluble salts, making them difficult to remove. Soil on clothes can introduce even more hardness minerals into the wash water. Continuous laundering in hard water can damage fibers and shorten the life of clothes by up to 40 percent.

    Bathing in Hard Water
    Bathing with soap in hard water leaves a film of sticky soap curd on the skin. The film may prevent removal of soil and bacteria. Soap curd interferes with the return of skin to its normal, slightly acid condition, and may lead to irritation. Soap curd on hair may make it dull, lifeless and difficult to manage.

    Problems with Hard Water in Water Boiler Systems and Pipework
    Hard water also contributes to inefficient and costly operation of water-using appliances. Heated hard water forms a scale of calcium and magnesium minerals (limescale deposits) that can contribute to the inefficient operation or failure of water-using appliances. Pipes can become clogged with scale that reduces water flow and ultimately requires pipe replacement. Limescale has been known to increase energy bills by up to 25%.

    Limescale in Solar Heating Systems
    Solar heating, often used for heating swimming pools is prone to limescale buildup, which can reduce the efficiency of the electronic pump. This, in turn can cause the overall system performance to deteriorate.


    How Does Your Water Measure Up?

    Slightly Hard Moderately Hard Hard Very Hard
    0.3 grains 4-7 grains 8-10 10 grains plus
    17.1-51.3 ppm or mg/L 68.4-119.7 ppm or mg/L 136.8-171 ppm or mg/L 188.1 ppm or mg/L plus



    Do I have Hard Water?
    For municipal water, call your water provider. They can tell you the average hardness and iron levels. If you have a private well, you can send us a water sample and we will test it FREE and review your options. Use this chart to estimate water softener size. To calculate total hardness, multiply total dissolved iron x 3, then add to total hardness.

    Picking the right water softener is an important step in the purification of your water. A water softener trades "hard" minerals in water for "soft" minerals. The typical trade is as calcium (hard mineral) enter a water softener it is traded for sodium (soft mineral). Inside a water softener are a bunch of chemical magnets called "ion exchange resin". These little chemical magnets do the trading. The more chemical magnets you have in a softener, the higher the capacity is. Capacity is the amount of gallons a softener will purify before you need to recharge (regenerate) it.

    Capacity of water softeners are measured in "grains" or "grain removal". This is a chemical measurement that has been used for a long time. One "grain per gallon" is equal to 17.1 parts per million. The average water in the United States has 10 grains of hardness per gallon. You can calculate the exact amount of hardness you have in your water using a water softener test kit. To calculate how much water you need to purify, multiply the number of people in your house by 80 (the average person uses 80 gallons of water per day). Then multiply that number by 1.5 for a safety factor. For an average family of 4 the calculation would look like this:


    People 4
    Gallons per person 80
    Gallons used per day 4 x 80 = 320
    Safety factor (x 1.5) = 480
    Grains of hardness 10
    Total grains used per day 4800


    Most homes use a one cubic foot water softener (1 ft3). Each cubic foot of resin will remove 30,000 to 36,000 grains of hardness. Each cubic foot will also flow 5 gallons per minute (g.p.m.). In selecting the right softener using the example above you would pick either a 30,000 grain softener and regenerate it about once a week, or pick a 60,000 grain softener and regenerate it about every 2 weeks.

    Regeneration is done using a timer (regenerates after a given time has passed) or by a meter valve (regenerates after a given amount of water is purified). A meter softener is the most efficient because if you use less water, it will regenerate less. A timer based softener is cleaner because the regeneration process cleans the resin and if you do not use a lot of water bacteria can accumulate inside the softener. Regenerating the softener at least once a week will help keep bacteria in control. `


    Grains of hardness Number of persons using water in household
    1 2 3 4 5 6 7
    0-10 24,000 32,000
    11-15 24,000 32,000
    16-20 24,000 32,000
    21-25 24,000 32,000 48,000
    26-30 24,000 32,000 48,000
    31-35 32,000 48,000
    36-40 32,000 48,000 64,000
    41-50 32,000 48,000 64,000
    51-70 48,000 64,000


    Please visit our section on water softening products.



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